New Molecular Systems Containing Silicon-Silicon Multiple Bonds
نویسندگان
چکیده
منابع مشابه
The Disilenes: Chemistry of Silicon-silicon Double Bonds
Three stable disilenes, Mes(R)Si=Si(R)Mes where R = mesityl, tert—butyl and (Me3Si)2N, have been prepared by photolysis of trisilanes and dimerization of the resulting ilylenes. X-ray crystallographic studies show Si=Si distances of "215 pm, about 20 pm shorter than for a Si—Si single bond. The silicon and attached carbon atoms are planar in the tert-butylmesityl compound but anti-pyramidal in ...
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ژورنال
عنوان ژورنال: Journal of Synthetic Organic Chemistry, Japan
سال: 2004
ISSN: 0037-9980,1883-6526
DOI: 10.5059/yukigoseikyokaishi.62.94